Someone asked me how to do a multiple tablerate, and actually I found it on magento forum. I am gonna list the code that I modified here:
\app\code\core\Mage\Shipping\Model\Carrier\Tablerate.php to \app\code\core\Mage\Shipping\Model\Carrier\Tablerate3.php or Tablerate(n).php
That is screen shot if you just copy my code to your site that will show on your Magento Admin Panel:

Note: This is my modified version, please read comment. In your case, your file should be similar to \app\code\core\Mage\Shipping\Model\Carrier\Tablerate.php, but except you will add a number after tablerate for Tablerate(n).
<?php
class Mage_Shipping_Model_Carrier_Tablerate3
extends Mage_Shipping_Model_Carrier_Abstract
implements Mage_Shipping_Model_Carrier_Interface
{
protected $_code = 'tablerate3';
protected $_default_condition_name = 'package_weight';
protected $_conditionNames = array();
public function __construct()
{
parent::__construct();
foreach ($this->getCode('condition_name') as $k=>$v) {
$this->_conditionNames[] = $k;
}
}
/**
* Enter description here...
*
* @param Mage_Shipping_Model_Rate_Request $data
* @return Mage_Shipping_Model_Rate_Result
*/
public function collectRates(Mage_Shipping_Model_Rate_Request $request)
{
if (!$this->getConfigFlag('active')) {
return false;
}
if (!$request->getConditionName()) {
$request->setConditionName($this->getConfigData('condition_name') ? $this->getConfigData('condition_name') : $this->_default_condition_name);
}
$result = Mage::getModel('shipping/rate_result');
$rate = $this->getRate($request);
/* My Edited Version. */
$smallShippingOk = $this->checkSmallPacket($request);
/* My Edited Version */
if (!empty($rate) && $rate['price'] >= 0
/*My Edited Version */ && $smallShippingOk /*My Edited Version */) {
$method = Mage::getModel('shipping/rate_result_method');
$method->setCarrier('tablerate3');
$method->setCarrierTitle($this->getConfigData('title'));
$method->setMethod('bestway');
$method->setMethodTitle($this->getConfigData('name'));
$shippingPrice = $this->getFinalPriceWithHandlingFee($rate['price']);
$method->setPrice($shippingPrice);
$method->setCost($rate['cost']);
$result->append($method);
}
return $result;
}
public function getRate(Mage_Shipping_Model_Rate_Request $request)
{
return Mage::getResourceModel('shipping/carrier_tablerate3')->getRate($request);
}
public function getCode($type, $code='')
{
$codes = array(
'condition_name'=>array(
'package_weight' => Mage::helper('shipping')->__('Weight vs. Destination'),
'package_value' => Mage::helper('shipping')->__('Price vs. Destination'),
'package_qty' => Mage::helper('shipping')->__('# of Items vs. Destination'),
),
'condition_name_short'=>array(
'package_weight' => Mage::helper('shipping')->__('Weight (and above)'),
'package_value' => Mage::helper('shipping')->__('Order Subtotal (and above)'),
'package_qty' => Mage::helper('shipping')->__('# of Items (and above)'),
),
);
if (!isset($codes[$type])) {
throw Mage::exception('Mage_Shipping', Mage::helper('shipping')->__('Invalid Table Rate code type: %s', $type));
}
if (''===$code) {
return $codes[$type];
}
if (!isset($codes[$type][$code])) {
throw Mage::exception('Mage_Shipping', Mage::helper('shipping')->__('Invalid Table Rate code for type %s: %s', $type, $code));
}
return $codes[$type][$code];
}
/**
* Get allowed shipping methods
*
* @return array
*/
public function getAllowedMethods()
{
return array('bestway'=>$this->getConfigData('name'));
}
/* My Own Function, original file does not have this function */
protected function checkSmallPacket($request) {
$items = $request->getAllItems();
foreach ($items as $item) {
$_product=$item->getProduct();
$_product->load($_product->getId());
if ($_product->getData('small_item') == "0")
return false;
}
return true;
}
/* My Own Function, original file does not have this function */
}